You may well be aware that your Mum and Sis will need two seperate visas (one for the UK and a Schengen) it might help their Schengen application if you will show the authorities that you are willing and able to support them whilst in Europe but as far as I know 'they' as the applicants would also need to submit proof of their finances e.g. 3 months bank statements with sufficient funds on it. I hope this helps. Some of the members might be able to give you some more insights as well. Good luck!